Alternative aluminum-based cocatalysts for the iron-catalyzed oligomerization of ethylene.

نویسندگان

  • Adrien Boudier
  • Pierre-Alain R Breuil
  • Lionel Magna
  • Hélène Olivier-Bourbigou
  • Pierre Braunstein
چکیده

Multinuclear aluminum cocatalysts have been obtained by the reaction of various phenols, alcohols or diols with trimethylaluminum and were used in situ or as isolated, well-defined species, for the activation of an iron(ii) or an iron(iii) pre-catalyst for the oligomerization of ethylene. The best cocatalyst candidate involves 2,2'-biphenol () in a /AlMe3 ratio of 2/3.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 29  شماره 

صفحات  -

تاریخ انتشار 2015